Transport and retention of positively charged zinc oxide nanoparticles in saturated porous media: Effects of metal oxides and clays.

The effects of metal oxides and clays on the transport of zinc oxide nanoparticles (ZnO-NPs) in saturated porous media were investigated under different ionic strength (IS) conditions. We studied the transport and retention behavior of ZnO-NPs for different types of porous media (untreated, acid treated, and acid-salt treated sand). The selected untreated sand was used as a representative sand, coated with both metal oxide and clay. The acid treated and acid-salt-treated sands were used and compared to investigate the effects of clays on the surface of the sand. In addition, the effects of clay particles in bulk solutions on the mobility and retention of ZnO-NPs were observed using bentonite as a representative clay particle. We found that the increased mobility of positively charged ZnO-NPs can be attributed to increasing charge heterogeneity of silica sand with metal oxides (mainly, iron oxide) and clays in untreated sand. No breakthrough of ZnO-NP was observed for acid-treated (presence of clays and absence of metal oxides) and acid-salt-treated sand (absence of both metal oxide and clays). Most of the injected ZnO-NPs were deposited on the surface of the sand near the column inlet. The transport of bentonite-facilitated ZnO-NPs was improved at the lowest IS (0.1 mM) (∼20%), whereas there was no difference in the mobility of ZnO-NPs at high IS solutions (1 mM and 10 mM). In particular, the breakthrough amount improved with increasing bentonite concentration. Classical Derjaguin-Landau-Verwey-Overbeek interactions help explain observed interactions between ZnO-NPs and sand as well as bentonite and sand.