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Metals in size-fractionated core sediments of Jiaozhou Bay, China: Records of recent anthropogenic activities and risk assessments.
Marine Pollution Bulletin 2018 Februrary
Total contents and chemical speciation of Co, Ni, Cu, Ga, Mo, Cd, In, Sn, Sb, V, W, Tl, Bi and U in size-fractionated (<32, 32-63 and >63μm) core sediments from Jiaozhou Bay were investigated to reveal their responses to anthropogenic activities. Metal contents showed a decreasing trend with increasing grain sizes. However, the loadings of metal fraction on <32, 32-63 and >63μm grain sizes were 16%, 47% and 37%, respectively. Anthropogenic fluxes and enrichment factors of metals in >63μm fraction were closely linked to anthropogenic activities, with an obvious increase in upper 27cm (1998-2015) and a slight decrease in 2009year. Metals (especially for Cd, Co, Cu and Ni) in >63μm fraction were more easily released, with the highest percentage of acid soluble form and lowest residual form. Thus, the size fraction of >63μm cannot be ignored.
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