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Diazophosphane HPN 2 .
Journal of the American Chemical Society 2022 November 30
Diazophosphane HPN2 , a heavy analogue of hydrazoic acid (HN3 ), has been synthesized at low temperature (10 K) through photolytic reactions of molecular nitrogen (N2 ) with phosphine (PH3 ) and phosphaketene (HPCO) under irradiations at 193 and 365 nm, respectively. The characterization of HPN2 and its isotopologues DPN2 and HP15 N2 by matrix-isolation IR and UV-vis spectroscopy is supported by quantum chemical calculations at the CCSD(T)-F12a/cc-pVTZ-F12 level of theory. Upon irradiation at 266 nm, the P-N bond in HPN2 breaks, whereas its photolysis at 193 nm generates the elusive phosphinyl radical • PN2 .
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