We have located links that may give you full text access.
1,2σ 3 λ 3 -Oxaphosphetanes and Their P -Chalcogenides-A Combined Experimental and Theoretical Study.
Although 1,2σ5 λ5 -oxaphosphetanes have been known for a long time, the "low-coordinate" 1,2σ3 λ3 -oxaphosphetanes have only been known since their first synthesis in 2018 via decomplexation. Apart from ligation of this P-heterocycle to gold(I)chloride and the oxidation using ortho -chloranil, nothing on their chemistry has been reported so far. Herein, we describe the synthesis of new 1,2σ3 λ3 -oxaphosphetane complexes ( 3a - e ) and free derivatives ( 4a - e ), as well as reactions of 4a with chalcogens and/or chalcogen transfer reagents, which yielded the P -chalcogenides ( 14 - 16a ; Ch = O, S, Se). We also report on the theoretical results of the reaction pathways of C -phenyl-substituted 1,2 σ3 λ3 -oxaphosphetanes and ring strain energies of 1,2σ4 λ5 -oxaphosphetane P -chalcogenides.
Full text links
Related Resources
Trending Papers
Renin-Angiotensin-Aldosterone System: From History to Practice of a Secular Topic.International Journal of Molecular Sciences 2024 April 5
Albumin: a comprehensive review and practical guideline for clinical use.European Journal of Clinical Pharmacology 2024 April 13
Revascularization Strategy in Myocardial Infarction with Multivessel Disease.Journal of Clinical Medicine 2024 March 27
Clinical practice guidelines on the management of status epilepticus in adults: A systematic review.Epilepsia 2024 April 13
Interstitial Lung Disease: A Review.JAMA 2024 April 23
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app