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Two new alkaloids from Portulaca oleracea L. and their anti-inflammatory and anticholinesterase activities.
Natural Product Research 2024 April 26
Two new alkaloids identified as 2-(((S,Z)-1-(1H-azirin-1-yl)-5-methylhex-1-en-3-yl)oxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol and (S,Z)-1-(1H-azirin-1-yl)-5-methylhex-1-en-3-ol, named olerazirin A ( 1 ), olerazirin B ( 2 ), together with five known alkaloids, identified as cyclo (L-Val-L-Ala) ( 3 ), cyclo-(glycyl-L-leucine) ( 4 ), cyclo-(Gly-Phe) ( 5 ), cyclo (Ser-Phe) ( 6 ), (3S,6S)-3-[(1R)-1-hydroxyethyl]-6-(phenyl-methyl)-2,5-piperazinedione ( 7 ) were obtained from Portulaca oleracea L. using a range of chromatographic techniques, 1D and 2D NMR, and high-resolution electrospray ionisation time-of-flight mass spectroscopic methods, in which the compounds 3 - 7 were isolated from P. oleracea for the first time. In addition, the results showed that the compounds 1 and 2 have anti-inflammatory activities and compounds 1 - 3 and 5 - 7 exhibit the anticholinesterase activities.
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