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Principal singlet fission properties of twisted acenes.
Acenes, especially tetracene derivatives, are used as singlet fission materials. The recent synthesis of Dodecaphenyl tetracene (showing end-to-end twist angles of 96-98 degrees) and twisted anthracene derivatives show that the synthesis of twisted linear oligoacenes is possible. Energy calculations and NICS-X-scan studies predict the twisted acenes may be better singlet fission materials compared to their planar analogues.
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