Hydrazine-Assisted Synthesis, Structures, Photoelectricity, and Photocatalysis of Ternary Mercury-Tellurostannate Hybrids with Transition-Metal Complexes.

Tellurostannates are traditionally prepared by multistep reactions using the tellurides SnTe, SnTe2 , K4 SnTe4 , or A 6 SnTe6 (A = K, Rb, or Cs) as precursors, which are usually prepared by the molten reaction of alkali metals Sn and Te under harsh synthetic conditions. Differently, ternary Hg-tellurostannate hybrids [Mn(en)3 ]HgSnTe3 (Te2 ) ( 1 ) (en = ethylenediamine), [Mn(dien)2 ]HgSnTe3 (Te2 ) ( 2 ), and [Fe(dien)2 ]HgSnTe3 (Te2 ) ( 3 ) (dien = diethylenetriamine) were synthesized by one-pot reactions using Sn and Te powders as starting materials in the presence of hydrazine under mild solvothermal conditions. In 1 , HgTe3 and SnTe4 units are joined via Te-sharing to form a 1-D polymeric chain [HgSnTe3 (Te2 )] n 2 n - , while the [HgSnTe3 (Te2 )] n 2 n - chains in 2 and 3 are composed of HgTe4 and SnTe4 units. The common feature of the [HgSnTe3 (Te2 )2- ] n chains in 1 - 3 is that they are constructed by both the telluride anion Te2- and the polytelluride anion Te2 2- . 1-3 exhibited strong photocurrent responses with current densities of 5.26, 3.38, and 3.94 μA cm-2 , respectively. They showed effective photocatalytic activities for methylene blue degradation with degradation ratios in the range of 85.3-94.6% after light irradiation for 80 min. Investigation of the photocatalytic mechanism showed that • O2 - radicals and h+ holes were the main active substances in the photodegradation.