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Chlorobenzene-driven palladium-catalysed lactonisation of benzoic acids.
RSC Advances 2024 January 3
Herein, we developed a palladium-catalysed C-H cyclisation of benzoic acids in chlorobenzene without additional oxidants. The key to the success of these reactions is the use of chlorobenzene, which serves a dual role as a solvent and an oxidant, thus providing a simple and efficient method for synthesising phthalides.
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