Preparation and characterization of hemicellulose films reinforced with amino polyhedral oligomeric silsesquioxane for biodegradable packaging.

Biomass is one of the powerful alternatives to petroleum-based packaging materials. Herein, carboxymethyl hemicellulose (CMH) based films (CPF) were prepared using a convenient strategy. The chains of CMH provided the necessary supporting matrix, and the aminopropyl polyhedral oligomeric silsesquioxane (POSS-NH2 ) regulated the thermal and barrier properties of the CPF. The secondary amide groups and hydrogen bond were appeared in chemical structure, and SEM-EDS results indicated the preferable dispersion and compatibility of POSS-NH2 in CPFs. The thermal degradation temperature (Tonset  > 260 °C), the coefficient of linear thermal expansion and glass transition temperature (Tg  > 130 °C) have been improved by introduction of POSS-NH2 . The tensile strength of CPF showed a higher level of 39.43 MPa with the POSS-NH2 loading of 20 wt%, which was 18.8 % higher than that of CMH film. More importantly, water vapor barrier property of films almost improved by two times, and its value is reduced to 18.82 g m-2  h-1 . The shelf life of blueberry was effectively extended by the CPF coating for one week compared with commercial PE film. Therefore, CPF films displayed effective thermal performances, water vapor barrier characteristic and biodegradability, which might be exploited in packaging material for food application.