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Three new Lycopodium alkaloids from Lycopodium japonicum.

Yu Zhu, Liao-Bin Dong, Zhi-Jun Zhang, Min Fan, Qin-Feng Zhu, Yan-Yan Qi, Yu-Chen Liu, Li-Yan Peng, Xing-De Wu, Qin-Shi Zhao
Journal of Asian Natural Products Research 2018 January 27
Three new Lycopodium alkaloids (1-3), together with 15 known alkaloids, were isolated from club moss Lycopodium japonicum. Their structures were determined by extensive spectroscopic analysis, including 1D and 2D NMR spectra. Compound 1 has an unusual β-oriented methyl group substituted at C-15 and an α-hydroxy cyclopentenone moiety. All new alkaloids were evaluated for the inhibition of T-type calcium channel.

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