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Electrochemical benzylic deuteration of p -QMs enabling the synthesis of benzylic deuterated diarylmethanes.
Organic & Biomolecular Chemistry 2024 May 8
Herein, electroreductive umpolung benzylic deuteration of p -QMs using cheap and easily accessible D2 O as a deuterium source is reported. Various value-added benzylic deuterated diarylmethanes can be synthesized without the requirement of noble metal catalysts, redox reagents, and strong bases. The establishment of this protocol will provide an alternative strategy for acquiring benzylic deuterated diarylmethanes.
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