Vibrational spectroscopy and dissociation dynamics of cyclohexyl hydroperoxide.

Organic hydroperoxides (ROOH) are ubiquitous in the atmospheric oxidation of volatile organic compounds (VOCs) as well as in low-temperature oxidation of hydrocarbon fuels. The present work focuses on a prototypical cyclic hydroperoxide, cyclohexyl hydroperoxide (CHHP). The overtone OH stretch (2 ν OH ) spectrum of jet-cooled CHHP is recorded by IR multiphoton excitation with UV laser-induced fluorescence detection of the resulting OH products. A distinctive IR feature is observed at 7012.5 cm-1 . Two conformers of CHHP are predicted to have similar stabilities (within 0.2 kcal mol-1 ) and overtone OH stretch transitions (2 ν OH ), yet are separated by a significant interconversion barrier. The IR power dependence indicates that absorption of three or more IR photons is required for dissociation of CHHP to cyclohexoxy (RO) and OH radical products. Accompanying high-level single- and multi-reference electronic structure calculations quantitatively support the experimental results. Calculations are extended to a range of organic hydroperoxides to examine trends in bond dissociation energies associated with RO + OH formation and compared with prior theoretical results.