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BP23C7: high-yield synthesis and application in constructing [3]rotaxanes and responsive pseudo[2]rotaxanes.
Organic & Biomolecular Chemistry 2024 Februrary 14
A biphenyl-23-crown-7 ether (BP23C7) is synthesized in 86% yield from commercially available starting materials. BP23C7 forms pseudo[2]rotaxane with a dibenzylammonium ion (DBA+ ), exhibiting a good association constant value ( k a = 1 × 103 M-1 ). Subsequently, fluorophoric properties of BP23C7 and anthracene terminated axles are blended to create responsive pseudo[2]rotaxanes. The "turn-on" fluorescence response of BP23C7 due to the addition of fluoride and chloride anions to pseudo[2]rotaxane systems has been investigated. Concomitant fluorescence quenching of the anthracene moiety of corresponding axles due to ion-pair formation has been addressed. Furthermore, two variants of [23]crown ethers, i.e. BP23C7 and o -xylene-23-crown-7 ether (X23C7), are applied for constructing homo[3]rotaxane architectures. A half-axle comprising of DBA+ moiety and a terminal olefin is mixed separately with two [23]crown ethers and subjected to self-metathesis using Grubbs' first-generation catalyst.
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