We have located links that may give you full text access.
Conformation-aggregation interplay in the simplest aliphatic ethers probed under high pressure.
IUCrJ 2024 January 2
The structures of the simplest symmetric primary ethers [(Cn H2n+1 )2 O, n = 1-3] determined under high pressure revealed their conformational preferences and intermolecular interactions. In three new polymorphs of diethyl ether (C2 H5 )2 O, high pressure promotes intermolecular CH...O contacts and enforces a conversion from the trans-trans conformer present in the α, β and γ phases to the trans-gauche conformer, which is higher in energy by 6.4 kJ mol-1 , in the δ phase. Two new polymorphs of dimethyl ether (CH3 )2 O display analogous transformations of the CH...O bonds. The crystal structure of di-n-propyl ether (C3 H7 )2 O, determined for the first time, is remarkably stable over the whole pressure range investigated from 1.70 up to 5.30 GPa.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app