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Journal Article
Research Support, U.S. Gov't, Non-P.H.S.
Bis(tetraphenylarsonium) hexafluoridotechnetate(IV) dihydrate: preparation, structure and spectroscopic analysis.
Acta Crystallographica. Section C, Structural Chemistry 2019 December 2
Reports of quadrivalent transition-metal fluoride salts containing bulky organic cations are limited. In this context, we prepared the bis(tetraphenylarsonium) hexafluoridotechnetate(IV) dihydrate salt, (C24 H20 As)2 [TcF6 ]·2H2 O, by a cation metathesis reaction of (NH4 )2 [TcF6 ] in water. This is the first report of an arsonium salt of the hexafluoridotechnetate(IV) dianion. (AsPh4 )2 [TcF6 ]·2H2 O crystallizes in the triclinic space group P-1. The [TcF6 ]2- anion adopts a slightly distorted octahedral geometry with an average Tc-F bond length of 1.933 Å. The cyclic voltammogram of (AsPh4 )2 [TcF6 ]·2H2 O in CH3 CN shows a one-electron reversible oxidation wave at 1.496 V.
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