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Near-infrared quadrupolar chromophores combining three-coordinate boron-based superdonor and -acceptor units.
Angewandte Chemie 2019 Februrary 20
In this work, two new quadrupolar A-π-D-π-A chromophores have been prepared featuring a strongly electron-donating diborene core and strongly electron-accepting dimesitylboryl (BMes2) and bis(2,4,6-tris(trifluoromethyl)phenyl)boryl (BFMes2) end groups. Analysis of the compounds by NMR spectroscopy, X-ray crystallography, cyclic voltammetry and UV-vis-NIR absorption and emission spectroscopy indicated that the compounds possess extended conjugated π-systems spanning their B4C8 cores. The combination of exceptionally potent π-donor (diborene) and π-acceptor (diarylboryl) groups, both based on trigonal boron, leads to very small HOMO-LUMO gaps, resulting in strong absorption in the near-IR region with maxima in THF at 840 and 1092 nm, respectively, and very high extinction coefficients of ca. 120,000 M-1cm-1. Both molecules also display weak near-IR fluorescence with small Stokes shifts.
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