Long-term creep deformations in colloidal calcium-silicate-hydrate gels by accelerated aging simulations.

When subjected to a sustained load, jammed colloidal gels can feature some delayed viscoplastic creep deformations. However, due to the long timescale of creep (up to several years), its modeling and, thereby, prediction has remained challenging. Here, based on mesoscale simulations of calcium-silicate-hydrate gels (CSH, the binding phase of concrete), we present an accelerated simulation method-based on stress perturbations and overaging-to model creep deformations in CSH. Our simulations yield a very good agreement with nanoindentation creep tests, which suggests that concrete creep occurs through the reorganization of CSH grains at the mesoscale. We show that the creep of CSH exhibits a logarithmic dependence on time-in agreement with the free-volume theory of granular physics. Further, we demonstrate the existence of a linear regime, i.e., wherein creep linearly depends on the applied load-which establishes the creep modulus as a material constant. These results could offer a new physics-based basis for nanoengineering colloidal gels featuring minimal creep.