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The role of charge in 1,2,3-triazol(ium)-based halogen bonding activators.

Alexander Dreger, Elric Engelage, Bert Mallick, Paul D Beer, Stefan M Huber
Chemical Communications : Chem Comm 2018 April 18
The influence of charge on the performance of monocationic and dicationic triazol(ium)-based halogen bond donors was investigated. Next to the activity in a halide abstraction benchmark reaction, halogen bonding was also evaluated via X-ray structural analyses and isothermal titration calorimetry.

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