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Isotropic rotation in amphidynamic crystals of stacked carbazole-based rotors featuring halogen-bonded stators.
Chemical Communications : Chem Comm 2016 October 26
Liquid-like dynamics of a covalent 1,4-phenylene rotator have been unveiled in 1 with a brominated stator showing type-II halogen bonds. This singular rotation is favored by synergistic molecular changes in stacked molecules, according to VT solid state NMR,1 H T1 relaxometry and VT X-ray experiments of this highly crystalline compound.
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