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Journal Article
Research Support, Non-U.S. Gov't
A chemoselective, one-pot transformation of aldehydes to nitriles.
Journal of Organic Chemistry 2012 October 20
This paper describes a procedure for direct conversion of aldehydes to nitriles using O-(diphenylphosphinyl)hydroxylamine (DPPH). Aldehydes are smoothly transformed to their corresponding nitriles by heating with DPPH in toluene. The reaction can be accomplished in the presence of alcohol, ketone, ester, or amine functionality.
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