Martina Alunni Cardinali, Maria Rachele Ceccarini, Irene Chiesa, Silvia Bittolo Bon, Tommaso Rondini, Manuel Serrano-Ruiz, Maria Caporali, Silvia Tacchi, Alberto Verdini, Caterina Petrillo, Carmelo De Maria, Tommaso Beccari, Paola Sassi, Luca Valentini
Despite the technological importance of semiconductor black phosphorus (BP) in materials science, maintaining the stability of BP crystals in organic media and protecting them from environmental oxidation remains challenging. In this study, we present the synthesis of bulk BP and the exploitation of the viscoelastic properties of a regenerated silk fibroin (SF) film as a biocompatible substrate to transfer BP flakes, thereby preventing oxidation. A model based on the flow of polymers revealed that the applied flow-induced stresses exceed the yield stress of the BP aggregate...
April 23, 2024: ACS Omega