Desulfurization

The development of stable and effective catalysts to convert toxic H2 S into high value-added sulfur is essential for production safety and environmental protection. However, the inherent defects of traditional iron- and zirconium-based catalysts, such as poor activity, high oxygen consumption, and low sulfur selectivity, limit their further developments and applications. Herein, the Fe-Zr bimetallic organic framework FeUIO-66( x ) with different cubic morphologies was synthesized via a facile solvothermal method...

Limited research has been conducted on ammonia (NH3 ) volatilization and greenhouse gases (GHGs) emissions in saline-alkali paddy fields, along with complex interaction involving various genes (16sRNA, amoA, narG, nirK, nosZ, and nifH). This study employed mesocosm-scale experiment to investigate NH3 volatilization and GHGs emissions, focusing on bacterial communities and genic abundance, in saline-alkali paddy fields with desulfurized gypsum (DG) and organic fertilizer (OF) amendments. Compared to the control (CK) treatment, DG and OF treatments reduced methane (CH4 ) and carbon dioxide (CO2 ) emissions by 78...

Selective oxidation of sulfides to sulfoxides is of great significance in the synthesis of pharmaceuticals, desulfurization of fuels, and detoxification of sulfur mustard chemical warfare agents. Designing selective catalysts to achieve the efficient transformation of sulfides to sulfoxides is thus highly desired. Herein, we report three transition metal-complex-functionalized polyoxovanadates, [Zn2 (BPB)2 ][V4 O12 ]·0.5BPB·H2 O ( 1 ), [Ni(BPB)(H2 O)][V2 O6 ]·2H2 O ( 2 ), and [Co(HBPB)2 ][V4 O12 ] ( 3 ) (BPB = 1,4-bis(pyrid-4-yl)benzene)), and explore their applications for selective oxidation of sulfides using H2 O2 as an oxidant...

Considering the synergistic carbon/pollution reduction and resource utilization, this study proposes recycling of manganese desulfurization slag to prepare low-temperature NH3 -SCR catalyst based on solid-state ion-exchange. The desulfurization slag was hydrothermally treated to be support under mild conditions, with the parent manganese oxide ore serving as active component. Hydrothermal treatment with a desulfurization slag to NaOH mass ratio of 1.0, at 100 °C for 10 h were actually cost-effective conditions for DS recycling...

The mix proportion of multi-source coal-based solid waste (CSW) for underground backfilling affects transportation and support performance of backfill materials, and even the backfilling cost. In this study, the optimal mix proportion of desulfurization gypsum (DG), furnace bottom slag (FBS) and gasification fine slag (GFS) is determined by the Response Surface Methodology-Box Behnken Design (RSM-BBD). Then the fluidity, bleeding rate, 3-day strength, 7-day strength and preparation cost are evaluation indicators, the optimal mix proportion of backfill materials is determined by the multi-objective decision-making method (MDM)...

Separation and reaction processes are key components employed in the modern chemical industry, and the former accounts for the majority of the energy consumption therein. In particular, hydrocarbon separation and purification processes, such as aromatics extraction, desulfurization, and denitrification, are challenging in petroleum refinement, an industrial cornerstone that provides raw materials for products used in human activities. The major technical shortcomings in solvent extraction are volatile solvent loss, product entrainment leading to secondary pollution, low separation efficiency, and high regeneration energy consumption due to the use of traditional organic solvents with high boiling points as extraction agents...

Since 2020, hybrid exhaust gas cleaning systems have been installed on container ships to be in line with the International Maritime Organisation regulations. This technology allows the removal of gaseous sulphur oxide compound before atmospheric rejection of exhaust gas with a concentration lower than 0.1% sulphur equivalent. To be also compliant with water discharge criteria, membrane processes used as a water treatment system have been complementary installed onboard maritime vessels. Objectives of our research are to demonstrate the membrane efficiency and performances for this field of application and their reliability for reaching future regulations...

Solidification/stabilization (S/S) is a typical technique to immobilize toxic heavy metals in Municipal solid waste incineration fly ash (MSWI FA). This study utilized blast furnace slag, steel slag, desulfurization gypsum, and phosphoric acid sludge to develop a novel metallurgical slag based cementing material (MSCM). Its S/S effects of MSWI FA and long-term S/S effectiveness under dry-wet circulations (DWC) were evaluated and compared with ordinary Portland cement (OPC). The MSCM-FA block with 25 wt.% MSCM content achieved 28-day compressive strength of 9...

To improve the cleanliness of coal-fired power plants' particulate matter emissions, a novel device (single-channel slit bubbling particle removal device (SCSB-PRD)) is proposed to improve the wet flue gas desulfurization system's (WFGDs) collaborative particle removal effect. Actual coal-fired flue gas was used to test the particle removal performance. The results showed that the flue gas temperature had no obvious effect on the scrubbing effect of the SCSB-PRD. The scrubbing space, scrubbing liquid volume, and flue gas flow rate effectively changed the gas-liquid flow state, and the bubbling state was the key factor in particle removal...

Wet flue gas denitrification offers a new route to convert industrial nitrogen oxides (NO x ) into highly concentrated nitrate wastewater, from which the nitrogen resource can be recovered to ammonia (NH3 ) via electrochemical nitrate reduction reactions (NITRRs). Low-cost, scalable, and efficient cathodic materials need to be developed to enhance the NH3 production rate. Here, in situ electrodeposition was adopted to fabricate a foamy Cu-based heterojunction electrode containing both Cu-defects and oxygen vacancy loaded Cu2 O (OVs-Cu2 O), which achieved an NH3 yield rate of 3...

Soil arsenic (As) contamination associated with the demolition of smelting plants has received increasing attention. Soil As can source from different industrial processes, and also participate in soil weathering, making its speciation rather complex. This study combined the usage of chemical sequential extraction and advanced spectroscopic techniques, e.g., time of flight secondary ion mass spectrometry (ToF-SIMS), to investigate the mineralogical transformation of soil As at different processing sites from a typical copper smelting plant in China...

Carbon capture and desulfurization of flue gases are crucial for the achievement of carbon neutrality and sustainable development. In this work, the "one-step" adsorption technology with high-performance metal-organic frameworks (MOFs) was proposed to simultaneously capture the SO2 and CO2 . Four machine learning algorithms were used to predict the performance indicators (NCO2+SO2 , SCO2+SO2/N2 , and TSN) of MOFs, with Multi-Layer Perceptron Regression (MLPR) showing better performance (R2  = 0.93)...

Deposition of metal nanoparticles onto the molybdenum disulfide (MoS2) nanosheets is an efficient method to tune the electronic structure of the MoS2 and maximize its catalytic performance towards the hydrogen evolution reaction (HER). Herein, we report the electrodeposition of Pd and Pt nanoparticles onto desulfurized MoS2 nanosheets (MoS2-x) to achieve an improved HER activity in an acidic electrolyte. The initial MoS2 powder was exfoliated and isolated through centrifugation, followed by electrochemical desulfurization to create defect sites...

Coal-fired power plants (CFPPs) are one of the most significant sources of mercury (Hg) emissions certified by the Minamata Convention, which has attracted much attention in recent years. In this study, we used the Web of Science and CiteSpace to analyze the knowledge structure of this field from 2000 to 2022 and then reviewed it systematically. The field of Hg emissions from coal-fired power plants has developed steadily. The research hotspots can be divided into three categories: (1) emission characterization research focused on speciation changes and emission calculations; (2) emission control research focused on control technologies; (3) environmental impact research focused on environmental pollution and health risk...

Biodegradation is an efficient and cost-effective approach to remove residual penicillin G sodium (PGNa) from the environment. In this study, the effective PGNa-degrading strain SQW1 (Sphingobacterium sp.) was screened from contaminated soil using enrichment technique. The effects of critical operational parameters on PGNa degradation by strain SQW1 were systematically investigated, and these parameters were optimized by response surface methodology to maximize PGNa degradation. Comparative experiments found the extracellular enzyme to completely degrade PGNa within 60 min...

Soil salinization has become a major challenge that severely threatens crop growth and influences the productivity of agriculture. It is urgent to develop effective management measures to improve saline-alkali soil. Thus, in this study, soil properties, microbial communities, and function under desulfurization gypsum (DE), soil amendment (SA), farm manure (FA), and co-application of desulfurization gypsum, soil amendment, and farm manure (TA) in a field experiment were examined by high-throughput sequencing...

Perceptron models have become integral tools for pattern recognition and classification problems in engineering fields. This study envisioned implementing artificial neural networks to forecast the performance of a mini-spray dryer for desulfurization activities. This work adopted k-fold cross-validation, a rigorous technique that evaluates model performance across multiple data segments. Several ANN models (21) were trained on data obtained from sulfation conditions, including sulfation temperature (120 °C-200 °C), slurry pH (4-12), stoichiometric ratio (0...

Certain factors hinder the commercialization of biodesulfurization process, including low substrate-specificity of the currently reported desulfurizing bacteria and restricted mass transfer of organic-sulfur compounds in biphasic systems. These obstacles must be addressed to clean organic-sulfur rich petro-fuels that pose serious environmental and health challenges. In current study, a dibenzothiophene desulfurizing strain, Gordonia rubripertincta W3S5 (source: oil contaminated soil) was systematically evaluated for its potential to remove sulfur from individual compounds and mixture of organic-sulfur compounds...

Developing reliable solid sorbents for efficient capture and removal of trace sulfur dioxide (SO2 ) under ambient conditions is critical for industrial desulfurization operations, but poses a great challenge. Herein, we focus on SNFSIX-Cu-TPA, a highly stable fluorinated MOF that utilizes SnF6 2- as pillars, for effectively capturing SO2 at extremely low pressures. The exceptional affinity of SNFSIX-Cu-TPA towards SO2 over CO2 and N2 was demonstrated through single-component isotherms and corroborated by computational simulations...

The recovery of low-grade waste heat from power plants greatly benefits energy conservation and emission reduction during electricity generation, while the waste heat utilization directly from desulfurization slurry is a significantly promising method to deeply recover such low-grade energy and has been developed in practical application. However, the pipe materials are subjected to erosion and corrosion challenges due to the high level of solid compositions and the presence of harmful ions, such as Cl-1 , which requires further evaluation under the condition of slurry heat exchange...