Excellent Ultraviolet Blocking Properties of Chiral Nematic Liquid Crystals.

We report the evaluation of chiral nematic liquid crystal (CNLC) in blocking ultraviolet (UV). The CNLC was coated on calcium fluoride substrate to measure the spectral transmittance, was measured to detect the UV blocking effect of CNLC. The results show that CNLC could reduce UVB (290-320 nm) by 99.9% and UVA (320-400 nm) by 95.6%. The barrier effect of cake-shaped semi-solidified CNLC microspheres was further investigated, and it was found that cake-shaped semi-solidified CNLC microspheres could reduce UVB by 58.2% and UVA by 34.1%. This is due to the chemical absorption property of CNLC, which has UV absorbing functional groups such as the benzene rings. And the physical reflection properties of CNLC could periodically reflect a certain wavelength of light. Liquid crystal (LC) is a rich set of soft materials with rod-like structures widely existing in nature, which is harmless to the human body and environment. Therefore, using CNLC's function of blocking UV, a new sunscreen can be developed.