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Modular Enzyme- and Light-Based Activation of the Cyclopropene-Tetrazine Ligation.
Chembiochem : a European Journal of Chemical Biology 2019 April 17
We describe a modular activation strategy for the cyclopropene-tetrazine ligation. The activation strategy uses chemically diverse enzyme or photolabile protecting groups as cyclopropene reactivity cages. Linkages between caging groups and the cyclopropene are via carbamates, permitting application of diverse cages to activate bioorthogonal reactivity by administering enzymes or light.
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