MENU ▼
Read by QxMD icon Read
search
OPEN IN READ APP
JOURNAL ARTICLE

Melting of CaSiO 3 Perovskite at High Pressure

James Braithwaite, Lars Stixrude
Geophysical Research Letters 2019 February 28, 46 (4): 2037-2044
30983646
Ab initio molecular dynamics simulations predict that CaSiO3 perovskite melts at 5600 K at 136 GPa, and 6400 K at 300 GPa, significantly higher than MgSiO3 perovskite. The entropy of melting (1.8 kB per atom) is much larger than that of many silicates at ambient pressure and of simple liquids and varies little with pressure. The volume of melting decreases rapidly with increasing pressure, to 3 % at 136 GPa, producing a melting slope that diminishes rapidly with pressure. We determine the melting temperature via the ZW method, combining the Z method, for which we clarify the theoretical basis, with a waiting time analysis. The ZW method results are internally confirmed by integrating the Clausius-Clapeyron equation, which also yields our results for the entropy and volume of melting. We find the eutectic composition on the MgSiO3 -CaSiO3 join to be x Ca  = 0.26 at 136 GPa and that metasilicate melt is denser than coexisting silicates.

Comments

You need to log in or sign up for an account to be able to comment.

No comments yet, be the first to post one!

Related Papers

Available on the App Store

Available on the Play Store
Remove bar
Read by QxMD icon Read
30983646
×

Search Tips

Use Boolean operators: AND/OR

diabetic AND foot
diabetes OR diabetic

Exclude a word using the 'minus' sign

Virchow -triad

Use Parentheses

water AND (cup OR glass)

Add an asterisk (*) at end of a word to include word stems

Neuro* will search for Neurology, Neuroscientist, Neurological, and so on

Use quotes to search for an exact phrase

"primary prevention of cancer"
(heart or cardiac or cardio*) AND arrest -"American Heart Association"