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JOURNAL ARTICLE
REVIEW
Small molecule activation by boron-containing heterocycles.
Chemical Society Reviews 2019 April 13
Most of the chemical and biological processes involving the fixation and transformation of small molecules have long been exclusive for metal complexes. Meanwhile, the last decades have seen a significant advance in main group chemistry that mimics transition-metal complexes, among which various boron-containing systems have been successful in mediating the small molecule activation. In this review, we focus on boron-containing heterocycles enabling the activation of σ- and π-bonds in small molecules, in conjunction with the proposed mechanisms.
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