One step synthesis of PANI/Fe2O3 nanocomposites and flexible film for enhanced NH3 sensing performance at room temperature.

Novel sea cucumber-shaped polyaniline/ferric oxide (PANI/Fe2O3) nanocomposites were synthesized using a simple and efficient one-step hydrothermal process, and further assembling the nanocomposites onto a polyethylene terephthalate (PET) flexible substrate. Through monitoring the resistance of the PANI/Fe2O3 nanocomposites thick film and PANI/Fe2O3-PET flexible sensors, the responses of the sensors are obtained to various 100 ppm gases including methanol, triethylamine, aniline and other five gases. It is found that two kinds of sensors exhibit a high selectivity towards NH3. The PANI/Fe2O3 nanocomposites-based sensor has a good response and a low detection limit (0.3 ppm) at room temperature (20±5oC). It also shows a good linearity relationship in a certain concentration of NH3. After assembling into the PANI/Fe2O3-PET flexible film sensor, the response of the sensor is significantly increased to 6.12 for 100 ppm NH3, the detection limit is as low as 0.5 ppm, and the sensor shows good stability and linearity, which is more conducive to such application of the material in wearable gas sensors.