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Indium- and zinc-catalyzed enantioselective amide propargylation of aldehydes with stannylated allenyl amides.
Organic & Biomolecular Chemistry 2019 Februrary 15
The catalytic enantioselective propargylation of aldehydes with newly prepared stannyl allenyl amides is described. The reaction has been accomplished by using catalytic amounts of indium chloride, zinc chloride, and a chiral BINOL derivative, affording amide-functionalized homopropargyl alcohols in excellent yields and enantioselectivities.
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