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Design, synthesis and study of a photochromic α,ω-diene: toward new classes of photoswitchable polymers.
Organic & Biomolecular Chemistry 2019 Februrary 14
A 4,5-dithienylimidazolium salt outfitted with pendant styrenyl groups was synthesized and studied. The salt was found to undergo reversible electrocyclization upon UV irradiation; subsequent exposure to visible light reversed the reaction. Acyclic diene metathesis (ADMET) polymerization of the salt afforded a novel fluorescent polyelectrolyte.
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