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Antioxidative Maillard Reaction Products Generated in Processed Aged Garlic Extract.
Journal of Agricultural and Food Chemistry 2019 Februrary 5
A powder formulation of aged garlic extract was heated at 100 oC for one day to obtain higher antioxidant activity determined with ABTS radical scavenging (ARS) and ORAC assays. Activity-guided fractionation afforded 12 new in vitro antioxidative Maillard-type products (Figure 1), α-[(2-formyl-5-hydroxymethyl)pyrrol-1-yl]arginine (3), 4-[7-hydroxy-6-(hydroxymethyl)-7,8-dihydro-6H-pyrano[2,3-b] pyrazine-3-yl]butane-1,2,3-triol (4) and 4-[6-(1,2-dihydroxyethyl)-6,7-dihydro-furo[2,3-b]pyrazin-3-yl]-butane-1,2,3-triol (5), α-[(2-formyl-5-hydroxymethyl)-pyrrol-1-yl] aspartic acid (12), 1-[5-(1,2-dihydroxyethyl)-2-oxotetrahydrofuran-3-yl]-5-(hydroxymethyl)-1H-pyrrole-2-carbaldehyde (14), 4-(6-ethyl-2-pyrazinyl)-1,2,3-butanetriol (17), α-[(2-formyl-5-hydroxymethyl)pyrrol-1-yl] glutamic acid (19), (S)-1-[(5-hydroxymethyl)furan-2-yl]methyl]-5-oxopyrrolidine-2-carboxylic acid (20), 3-hydroxy-1H-[{5-(hydroxymethyl)furan-2-yl}methyl]-2,5-dioxo-3-pyrrolidine acetic acid (21), (E)-4-(5-methylpyrazin-2-yl)but-3-ene-7,2-diol (23), 4-acetyl-6-(hydroxymethyl)picolinic acid (24), (E)-4-(6-methylpyrazin-2-yl)but-3-ene-1,2-diol (26) and 14 known compounds (Figure 1, 1, 2, 6-11, 13, 15, 16, 18, 22 and 25) which were characterized via 1D/2D-NMR, CD spectroscopy, and mass spectrometry. ARS and ORAC activities of these antioxidants ranged from 0.01 to 0.49 μmol TE/μmol and from 0.01 to 3.50 μmol TE/μmol, respectively. Additionally, plausible formation pathways for the new organic acid-type products (15, 20 and 21) were proposed based on proving their generation in model reactions detected via LC-MS/MS.
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