We have located links that may give you full text access.
Synthesis and Characterization of the New Manganese Hydroxide Chloride γ-Mn(OH)Cl.
European Journal of Inorganic Chemistry 2018 November 16
A new modification of Mn(OH)Cl was obtained under high-pressure/high-temperature conditions in a Walker-type multianvil device. The pale pink, hygroscopic compound crystallizes in the orthorhombic space group Pnma (no. 62) with a = 602.90(4), b = 350.98(2), c = 1077.69(7) pm, and V = 228 × 106 pm3 . The layered centrosymmetric structure consists of edge-sharing Mn(OH)3 Cl3 octahedra arranged in sheets parallel to the (001) plane. The comparatively long H ··· Cl distance of 275 pm suggests only weak hydrogen bonds between neighboring layers. Spin-polarized scalar-relativistic DFT+ U calculations predict a non-conducting magnetically ordered ground state with a band gap of at least 3.2 eV and an effective magnetic moment of 4.65 µB /f. u. The experimentally determined magnetic response of Mn(OH)Cl is paramagnetic in the range of 10-300 K. The estimated moment of 5.6 µB /f. u. indicates the high-spin d 5 configuration of manganese(II). We find hints for a long-range magnetic ordering below 10 K.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app