Biomimetic Solid-State Zn2+ Electrolyte for Corrugated Structural Batteries.

Batteries based on divalent metals, such as Zn/Zn+2 pair, represent attractive alternatives to lithium-ion chemistry due to their high safety, reliability, earth-abundance and energy density. However, archetypal Zn batteries are bulky, inflexible, non-rechargeable, and contain a corrosive electrolyte. Suppression of the anodic growth of Zn dendrites is essential for resolution of these problems and requires materials with nanoscale mechanics sufficient to withstand mechanical deformation from stiff Zn dendrites. Such materials must also support rapid transport Zn2+ ions necessary for high Coulombic efficiency and energy density, which makes the structural design of such materials a difficult fundamental problem. Here we show that it is possible to engineer a solid Zn2+ electrolyte as a composite of branched aramid nanofibers (BANFs) and poly(ethyleneoxide) by using the nanoscale organization of articular cartilage as a blueprint for its design. The high stiffness of the BANF network combined with the high ionic conductivity of soft poly(ethyleneoxide) enable effective suppression of dendrites and fast Zn2+ transport. The cartilage-inspired composite displays the ionic conductance 10x higher than the original polymer. The batteries constructed using the nanocomposite electrolyte are rechargeable and have Coulombic efficiency of 96%-100% after 50-100 charge-discharge cycles. Furthermore, the biomimetic solid-state electrolyte enables the batteries to withstand not only elastic deformation during bending but also plastic deformation. This capability make them resilient to different type of damage and enables shape modification of assembled battery to improve the ability of the battery stack to carry structural load. The corrugated batteries can be integrated into body elements of unmanned aerial vehicles (UAVs) as auxiliary charge storage devices. This functionality was demonstrated by replacing the covers of several small drones with pouch-like Zn/BANF/MnO2 cells, resulting in the extension of the total flight time. These findings open a pathway to design and utilization of corrugated structural batteries in the future transportation industry and other fields of use.