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Al(OCArF3) 3 - a thermally stable Lewis superacid.

Chemical Science 2018 November 22
The adduct free Lewis superacid Al(OCArF3)3 was obtained by the reaction of ArF3COH with AlEt3 and fully characterized (ArF = C6 F5 ). It comprises a high thermal stability up to 180 °C and a distinct reactivity towards Lewis bases, as exemplified by the isolation of the neutral adducts Al(OCArF3)·D (D = MeCN, THF, Et2 O, pyridine, OPEt3 ), the fluoride complexes [Q][FAl(OCArF )3 ] (Q+ = Cs+ , Ag+ , Tl+ , [S(NMe2 )3 ]+ , [Ph3 C]+ , Li+ , [NBu4 ]+ , [FeCp2 ]+ ) and the chloride complex [Ph3 C][ClAl(OCArF )3 ].

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