Molecular-Level CuS@S Hybrid Nanosheets Constructed by Mineral Chemistry for Energy Storage Systems.

The transition-metal sulfide, CuS, is deemed a promising material for energy storage, mainly derived from its good chemisorption and conductivity, whilst serious capacity fading limits its advancement within reversible lithium storage. Learning from the gold extraction method utilizing a lime-sulfur-synthetic-solution, CuS@S hybrid utilizing CaSx as both the sulfur resource and reductant-oxidant is prepared, which is an efficient approach to apply the metallurgy for the preparation of electrode materials. Regulating the amount of CuCl2, the CuS@S is induced to reach a molecular-level hybrid. When utilized as anode within lithium-ion battery, it presents special capacity of 514.4 mAh g-1 at 0.1 A g-1 over 200 cycles. Supported by the analyses of pseudo-capacitive behaviors, it is confirmed that the CuS matrix with the suitable content of auxiliary sulfur could improve the durability of the CuS-based anode. Expanding the wider application within lithium-sulfur battery, the synchronous growth of CuS@S exhibits stronger chemisorption with polysulfides than the mechanical mixture of CuS and S. A suite of in-situ electrochemical impedance spectroscopy further investigates the stable resistances of the CuS@S within the charge/discharge process, corresponding to the reversible structure evolution. This systematic work may provide a practical fabricating route of metal sulfides for scalable energy storage applications.