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Potassium-Promoted Molybdenum Carbide as a Highly Active and Selective Catalyst for CO2 Conversion to CO

Marc D Porosoff, Jeffrey W Baldwin, Xi Peng, Giannis Mpourmpakis, Heather D Willauer
ChemSusChem 2017 June 9, 10 (11): 2408-2415
28426923
The high concentration of CO2 bound in seawater represents a significant opportunity to extract and use this CO2 as a C1 feedstock for synthetic fuels. Using an existing process, CO2 and H2 can be concurrently extracted from seawater and then catalytically reacted to produce synthetic fuel. Hydrogenating CO2 directly into liquid hydrocarbons is exceptionally difficult, but by first identifying a catalyst for selective CO production through the reverse water-gas shift (RWGS) reaction, CO can then be hydrogenated to fuel through Fischer-Tropsch (FT) synthesis. Results of this study demonstrate that potassium-promoted molybdenum carbide supported on γ-Al2 O3 (K-Mo2 C/γ-Al2 O3 ) is a low-cost, stable, and highly selective catalyst for RWGS over a wide range of conversions. These findings are supported by X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and density functional theory calculations.

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