JOURNAL ARTICLE

Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate

Narayanaru Sreekanth, Mohammed Azeezulla Nazrulla, Thazhe Veettil Vineesh, Krishnamurty Sailaja, Kanala Lakshminarasimha Phani
Chemical Communications: Chem Comm 2015 November 18, 51 (89): 16061-4
26394046
Herein we report the electrocatalytic activity of boron-doped graphene for the reduction of CO2. Electrolysis takes place at low overpotentials leading exclusively to formate as the product (vis-à-vis benchmark Bi catalyst). Computational studies reveal mechanistic details of CO2 adsorption and subsequent conversion to formic acid/formate.

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