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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
13²,17³-Cyclopheophorbide b enol as a catabolite of chlorophyll b in phycophagy by protists.
FEBS Letters 2013 August 20
Both 13(2),17(3)-cyclopheophorbide a and b enols were produced along with ingestion of green microalgae containing chlorophylls a and b by a centrohelid protist (phycophagy). The results suggest that chlorophyll b as well as chlorophyll a were directly degraded to colored yet non-phototoxic catabolites in the protistan phycophagic process. Such a simple process by the predators makes a contrast to the much sophisticated chlorophyll degradation process of land plants and some algae, where phototoxicity of chlorophylls was cancelled through the multiple enzymatic steps resulting in colorless and non-phototoxic catabolites.
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