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An unprecedented acylamide-functionalized 2D → 3D microporous metal-organic polycatenation framework exhibiting highly selective CO2 capture.

An acylamide-functionalized 3D microporous metal-organic framework built on Zn2 clusters with mixed H3bcta and dipy ligands, which shows unprecedented 2D → 3D polycatenation based on dipy-pillared honeycomb bilayers, and exhibits highly selective CO2 capture.

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