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Biomimetic catalysis of a porous iron-based metal-metalloporphyrin framework.

Yao Chen, Tran Hoang, Shengqian Ma
Inorganic Chemistry 2012 December 4
A porous metal-metalloporphyrin framework, MMPF-6, based upon an iron(III)-metalated porphyrin ligand and a secondary binding unit of a zirconium oxide cluster was constructed; MMPF-6 demonstrated interesting peroxidase activity comparable to that of the heme protein myoglobin as well as exhibited solvent adaptability of retaining the peroxidase activity in an organic solvent.

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