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An anion exchange approach to Bi2WO6 hollow microspheres with efficient visible light photocatalytic reduction of CO2 to methanol.

Hefeng Cheng, Baibiao Huang, Yuanyuan Liu, Zeyan Wang, Xiaoyan Qin, Xiaoyang Zhang, Ying Dai
Chemical Communications : Chem Comm 2012 October 10
An anion exchange strategy is explored to synthesize Bi(2)WO(6) hollow microspheres based on the microscale Kirkendall effect. The as-prepared Bi(2)WO(6) hollow microspheres display high CO(2) adsorption capacity and visible light photocatalytic conversion efficiency of CO(2) into methanol without the aid of any co-catalyst.

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