We have located links that may give you full text access.
EVALUATION STUDIES
JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
RESEARCH SUPPORT, U.S. GOV'T, NON-P.H.S.
Dichlorodiphenyltrichloroethane determination in air by thermal desorption gas chromatography-mass spectrometry.
Pest Management Science 2012 October
BACKGROUND: Current quantitative methods for airborne dichlorodiphenyltrichloroethane (DDT) require collection and extraction times of ≥ 12 h. The aim of this study was to develop a method for quantifying airborne DDT with a short (<4 h) collection and analysis time.
RESULTS: Precision [relative standard deviation (RSD)] for each calibration point (0.8-9.0), linearity (R(2) = 0.99) and apparent recovery (R' = 96.5%) were determined from thermal desorption (TD) gas chromatography-mass spectrometry (GC-MS) analyses of Tenax-TA-packed sampling tubes spiked with 1-250 ng of DDT. Recovery of (13) C-labeled 4,4'-DDT from tubes spiked before and after air sampling was 97.3 and 90.3% respectively. DDT was detected and quantified in 1-3 L samples of air collected during 10-180 min sampling events. A significant difference was observed in DDT air concentration between 28 and 33 °C during microchamber studies.
CONCLUSIONS: The results demonstrate that the TD GC-MS method developed in this study is precise, reproducible and linear over the span of 1-250 ng of DDT spiked onto TD tubes. By avoiding dilution of the sample, the method described allows the measurement of DDT vapor concentrations during short sampling periods (10-180 min) relevant to mosquito behavior studies.
RESULTS: Precision [relative standard deviation (RSD)] for each calibration point (0.8-9.0), linearity (R(2) = 0.99) and apparent recovery (R' = 96.5%) were determined from thermal desorption (TD) gas chromatography-mass spectrometry (GC-MS) analyses of Tenax-TA-packed sampling tubes spiked with 1-250 ng of DDT. Recovery of (13) C-labeled 4,4'-DDT from tubes spiked before and after air sampling was 97.3 and 90.3% respectively. DDT was detected and quantified in 1-3 L samples of air collected during 10-180 min sampling events. A significant difference was observed in DDT air concentration between 28 and 33 °C during microchamber studies.
CONCLUSIONS: The results demonstrate that the TD GC-MS method developed in this study is precise, reproducible and linear over the span of 1-250 ng of DDT spiked onto TD tubes. By avoiding dilution of the sample, the method described allows the measurement of DDT vapor concentrations during short sampling periods (10-180 min) relevant to mosquito behavior studies.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app