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JOURNAL ARTICLE
RESEARCH SUPPORT, NON-U.S. GOV'T
The unique rht-MOF platform, ideal for pinpointing the functionalization and CO2 adsorption relationship.
Chemical Communications : Chem Comm 2012 Februrary 2
The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO(2) uptake in the resultant rht-MOF.
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