Ethanol and water adsorption in methanol-derived ZIF-71

Ryan P Lively, Michelle E Dose, Joshua A Thompson, Benjamin A McCool, Ronald R Chance, William J Koros
Chemical Communications: Chem Comm 2011 August 14, 47 (30): 8667-9
A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions.

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