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High capacity gas storage by a 4,8-connected metal-organic polyhedral framework.

Chenrong Tan, Sihai Yang, Neil R Champness, Xiang Lin, Alexander J Blake, William Lewis, Martin Schröder
Chemical Communications : Chem Comm 2011 April 22
The polyhedral complex [Cu(4)L(H(2)O)(4)]solv (NOTT-140) shows a 4,8-connected structure of rare scu topology comprising octahedral and cuboctahedral cages; desolvated NOTT-140a shows a total CO(2) uptake of 314.6 cm(3) (STP) cm(-3) at 20 bar, 293 K, and a total H(2) uptake of 6.0 wt% at 20 bar, 77 K.

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