JOURNAL ARTICLE

Structure of GeSe4-In and GeSe5-In glasses

I Kaban, P Jóvári, T Petkova, P Petkov, A Stoilova, W Hoyer, B Beuneu
Journal of Physics. Condensed Matter: An Institute of Physics Journal 2010 October 13, 22 (40): 404205
21386566
(Ge(0.2)Se(0.8))(100-x)In(x) and (Ge(0.17)Se(0.83))(100-x)In(x) (x = 0, 5, 10, 15 at.%) chalcogenide glasses have been studied with high-energy x-ray diffraction, neutron diffraction and extended x-ray absorption spectroscopy at Ge, Se and In K-edges. The experimental data were modelled simultaneously with the reverse Monte Carlo simulation method. GeSe(4/2) tetrahedra are shown to be the main structural units in the binary and ternary glasses investigated. Indium bonds to the excess Se atoms in the ternary Ge-Se-In glasses. While the majority of In atoms have three Se neighbours, some In atoms may be tetrahedrally coordinated by Se.

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