Decreased DOC concentrations in soil water in forested areas in southern Sweden during 1987-2008.

During the last two decades, there is a common trend of increasing concentrations of dissolved organic carbon (DOC) in streams and lakes in Europe, Canada and the US. Different processes have been proposed to explain this trend and recently a unifying hypothesis was presented, concluding that declining sulphur deposition and recovery from acidification, is the single most important factor for the long-term DOC concentration trends in surface waters. If this recovery hypothesis is correct, the soil water DOC concentrations should increase as well. However, long-term soil water data from Sweden and Norway indicate that there are either decreasing or indifferent DOC concentrations, while positive DOC trends have been found in the Czech Republic. Based on the soil water data from two Swedish integrated monitoring sites and geochemical modelling, it has been shown that depending on changes in pH, ionic strength and soil Al pools, the DOC solubility might be positive, negative or indifferent. In this study, we test the acidification recovery hypothesis on long-term soil water data (25 and 50cm soil depth) from 68 forest covered sites in southern Sweden, showing clear signs of recovery from acidification. The main aim was to identify potential drivers for the DOC solubility in soil solution by comparing trends in DOC concentrations with observed changes in pH, ionic strength and concentrations of Al(n+). As in earlier Swedish and Norwegian studies, the DOC concentrations in soil water decreased or showed no trend. The generally small increases in pH (median <0.3 pH units) during the investigation period seem to be counterbalanced by the reduced ionic strength and diminished Al concentrations, increasing the organic matter coagulation. Hence, opposite to the conclusion for surface waters, the solubility of organic matter seems to decrease in uphill soils, as a result of the acidification recovery.