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Journal Article
Research Support, Non-U.S. Gov't
Reaction-based fluorescent sensing of Au(I)/Au(III) species: mechanistic implications on vinylgold intermediates.
Organic Letters 2010 Februrary 6
A rhodamine-derived alkyne shows turn-on fluorescence change only toward Au(I)/Au(III) species among various other metal species examined. A formyloxazole compound is formed as the major product in aqueous media, presumably via a vinylgold intermediate, which casts new mechanistic implications on vinylgold intermediates.
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