We have located links that may give you full text access.
Journal Article
Research Support, Non-U.S. Gov't
Cetylpyridinium chloride at the mica-water interface: incomplete monolayer and bilayer structures.
Langmuir : the ACS Journal of Surfaces and Colloids 2009 January 21
Monte Carlo simulations of the interface between the cleaved surface of muscovite mica and aqueous cetylpyridinium chloride (CPCl) solution at ambient conditions are reported. Simulation results reveal that monolayer or bilayer aggregates of CP(+) ions at the muscovite-water interface remain incomplete up to a CP(+) coverage compensating the negative charge of muscovite. It is predicted that at this CP(+) coverage only a partial desorption of K(+) ions occurs and the two aggregates can be distinguished with help of the X-ray reflectivity technique. Formation of inner-sphere and outer-sphere adsorption complexes of CP(+) ions at distances of approximately 3 A and approximately 5 A, respectively, from the surface is observed. Despite an increasing adsorption of CP(+) ions, the structure of the adsorbed water film is largely preserved within approximately 5 A from the surface. A strong decrease of water density beyond this distance and formation of "adsorbed K(+)"-Cl(-) ion pairs result in coadsorption of Cl(-) in an amount equivalent to 1/4 of the negative charge of muscovite as close as approximately 4.3-4.8 A to the surface for the incomplete bilayer aggregate. For the incomplete monolayer aggregate, no segregation between K(+) and CP(+) ions and a displacement of K(+) ions into the adsorption sites approximately 1.6 A from the surface are observed.
Full text links
Related Resources
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app
All material on this website is protected by copyright, Copyright © 1994-2024 by WebMD LLC.
This website also contains material copyrighted by 3rd parties.
By using this service, you agree to our terms of use and privacy policy.
Your Privacy Choices
You can now claim free CME credits for this literature searchClaim now
Get seemless 1-tap access through your institution/university
For the best experience, use the Read mobile app