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Supramolecular nanoribbons and nanoropes generated from hydrogen-bonded supramolecular polymers containing perylene bisimide chromophores.
Organic Letters 2007 March 16
A perylene bisimide anchored with melamine hydrogen-bonding units has been prepared, and its supramolecular polymerization upon binding with N-dodecylcyanurate (CA) was examined. The resulting flexible supramolecular polymers self-organized via a pi-pi stacking interaction between perylene chromophores, affording ribbonlike aggregates in cyclic alkanes and ropelike aggregates in acyclic alkanes to form gels. [structure: see text]
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