JOURNAL ARTICLE

Metal-metal interactions in dinuclear ruthenium complexes containing bridging 4,5-di(2-pyridyl)imidazolates and related ligands

Jonathan W Slater, Deanna M D'Alessandro, F Richard Keene, Peter J Steel
Dalton Transactions: An International Journal of Inorganic Chemistry 2006 April 28, (16): 1954-62
16609765
The dinuclear bis(2,2'-bipyridine)ruthenium complex of 4,5-di(2-pyridyl)imidazolate has been prepared and separated into its (meso and rac) diastereoisomers. The 2-phenyl substituted analogue forms the meso isomer selectively. All three complexes have been characterised by 1H NMR and X-ray crystallography. Electrochemical measurements and spectroelectrochemistry of the mixed-valence states reveal strong metal-metal interactions and IVCT bands that are highly dependent on the electrolyte.

Full Text Links

Find Full Text Links for this Article

Discussion

You are not logged in. Sign Up or Log In to join the discussion.

Related Papers

Remove bar
Read by QxMD icon Read
16609765
×

Save your favorite articles in one place with a free QxMD account.

×

Search Tips

Use Boolean operators: AND/OR

diabetic AND foot
diabetes OR diabetic

Exclude a word using the 'minus' sign

Virchow -triad

Use Parentheses

water AND (cup OR glass)

Add an asterisk (*) at end of a word to include word stems

Neuro* will search for Neurology, Neuroscientist, Neurological, and so on

Use quotes to search for an exact phrase

"primary prevention of cancer"
(heart or cardiac or cardio*) AND arrest -"American Heart Association"